1.For an npn transistor, the voltage at the collector VC must be greater than the voltage at the emitter VE by at least a few tenths of a volt; otherwise, current will not flow through the collector-emitter junction, no matter what the applied voltage at the base. For pnp transistors, the emitter voltage must be greater than the collector voltage by a similar amount.
2. For the npn transistor, there is a voltage drop from the base to the emitter of 0.6 V. For a pnp transistor, there is also a 0.6 V rise from the base to the emitter. In terms of operation, this means that the base voltage VB of an npn transistor must be at least 0.6 V greater that the emitter voltage VE; otherwise, the transistor will not pass emitter-to-collector current. For a pnp transistor, VB must be at least 0.6 V less than VE; otherwise, it will not pass collector-to-emitter current.